11th November 2018

Whisky Production: Distillation

Distillation is the process of separating the components from within a liquid by taking advantage of their different boiling points. The wash that was produced in the previous step – mashing and fermentation – contains roughly 10% alcohol, a bunch of flavour compounds and a whole lot of water. The aim of distillation is to increase the alcohol content while concentrating the desired aromas and filtering out unwanted compounds.

Water boils at 100°C, ethanol at 78.37°C. By keeping the area at the top of the still between these two temperatures, the water will condense and fall back into the pot, whereas the alcohol vapour will be allowed to continue around the head and into the lyne arm. This vapour is then collected and condensed back into liquid.

Single malt Scotch whisky is generally distilled twice, although there are of course exceptions. Several distilleries distil their whisky three times, which is more typical for Irish whiskey. Springbank famously distil their product 2.5 times! Grain whisky, the basis for blended whisky, is distilled using a continuous distillation process. We will cover blended whisky fully in a future article.

Still design: What is a pot still?

The stills in which single malt Scotch whisky is produced are, by law, made from copper. They consist of a large pot base with a tall, thin neck (known as a “swan neck”), which ends in an angled turn into a pipe called a lyne arm. This pipe is connected to a condenser which will cool the vapours coming off the still back into liquid form.

The liquid coming off the stills then flows through a receiving vessel called a spirit safe. This is a locked glass box where the stillman can check the spirit and decide when to start collecting the liquid that will become whisky. The spirit safe is kept locked by the local excise official to prevent alcohol from being siphoned off before it can be measured for tax purposes.

First distillation: The wash still

The first still, into which the wash is filled, is called the wash still. When heated, the ethanol, as well as various compounds, will begin to vaporise and rise in the still. Much of the vapour will condense on the sides of the still and fall back into the pot. This reflux ensures that only the lighter, desirable compounds reach the top of the still. The copper in the stills also helps to strip away the heavier compounds, such as sulphur, ensuring a lighter spirit.

Once the vapour has made it around the head and into the lyne arm, it reaches the condensors. Here cold water flows along the sides of the pipes to cool the vapour back into liquid form. The liquid, now called low wines passes through the spirit safe and is collected in the low wines receiver. The liquid coming off the still first is higher in alcohol (roughly 45% ABV); as the distillation progresses the alcohol content falls. When the alcohol content of the low wines coming off the still reaches around 1% the distillation is deemed complete. The collected low wines will have be approximately 25% ABV.

Second distillation: The spirit still

The second distillation takes place in the spirit still. It is similar to the first, however the resulting liquid is separated into three “cuts”: heads, hearts and tails.

The heads, also called foreshots, are the first runnings of the spirit still. They contain all of the lighter compounds that vaporise first, including volatile and aromatic compounds such as ethyl acetate. These are not deemed worthy of collection and are rerouted via the spirit safe back to the low wines receiver. They will be distilled again with the next batch.

After approximately 10 – 30 minutes, once the alcohol content has fallen to roughly 75% ABV, the stillman will turn a handle in the spirit safe and begin collecting the hearts. The hearts, also called the middle cut, contain all of the desirable flavours and aroma compounds. This liquid will be collected in the spirit receiver and will later, after maturation, become whisky. For now though it is called new make spirit.

The choice of when to begin and stop collecting the hearts has a major impact on the level of compounds in the final spirit. Therefore this decision has a significant effect on the final character and is a major contributor to the differences between whiskies from separate distilleries. Another contributing factor to the differences between distilleries is the shape of the still and the angle of the lyne arm. Shape and height both influence the level of copper contact and reflux. Taller stills with upward reaching lyne arms generally result in lighter whiskies.

Collection of the new spirit lasts roughly 3 hours, when the alcohol content falls to roughly 60% ABV, before the tails begin to run off the still. The tails, also called the feints, contain all of the heavier compounds, such as fusel oils, that are not desirable in the spirit. The stillman will again turn the handle on the spirit safe and redirect the tails to the low wines receiver. Again these will be distilled in the next run.

The collected new make will now be transferred to casks for maturation.

Want to learn more about whisky production?

Take a look at the next step in the production process: Maturation and Bottling.

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Whisky Production: Malting Barley

As mentioned in our previous article, "What is whisky made from?“, whisky is made from grains. Malt whisky more specifically is made from barley. The yeast added during the fermentation stage however are unable to use the starch present in the barley to produce alcohol. The starch must therefore first be converted into fermentable sugars. This is achieved through a process known as malting. If left out in the field, this conversion of starch to sugar would occur naturally. Cytase and protease enzymes within the grains would begin to degrade the cell walls, making starch available for α-amylase and β-amylase enzymes to turn into sugar. It is this sugar that the barley embryo would then normally use as fuel to grow. Malting takes advantage of this natural process by tricking the barley into thinking it is time to grow. This sets off the chain of events to convert the starches into sugars which is then abruptly stopped before the embryo can consume them, after all, we need them to make alcohol. The malting process consists of three stages: Steeping, germination, and kilning. The first stage in the malting process sees the grains steeped in water. The purpose of this is to increase the moisture content of the grain from 12% to around 45%. The grains are soaked in water for a period of several hours, during which time air is blown through the grains to ensure enough oxygen is present for the developing embryos. Once hydrated the enzymes begin to degrade the cell walls making the starch available and germination can begin. The water is then drained and the wet barley is allowed to rest in air, helping to control the heat and carbon dioxide levels produced during germination. This process is repeated 2 to 3 times over a period of 2 to 3 days in order to ensure all the grains are evenly hydrated and germinating. Once germination has started, the damp barley – now called green malt - is transferred to a germination vessel to allow further enzyme development. This was traditionally a malting floor where the grain would need to be turned by hand using a shovel – this led to an injury in many maltsters known as monkey shoulder. These days most malting is done in modern, industrial malting towers. However, some distilleries (Laphroaig for example) still produce a fraction of their own malt in the traditional manner and seeing this being done is a real highlight on their distillery tours. Throughout this stage the green malt has to be turned frequently to ensure an even distribution of temperature and moisture and to prevent the grains from sticking together. Modern facilities have perforated floors where air can be blown through the grain bed to control temperature and moisture. Most also incorporate some kind of mechanical turning arm to mix the grain bed and keep it loose. The germination stage lasts approximately 5 days, depending on the required malt specifications.

As mentioned above, the germination process has to be stopped before the embryo consumes the sugars. This is done in the kiln – the chimney of which is the large pagoda roof featured on the majority of distilleries – by blowing hot air through the grains. It is at this stage that many whiskies pick up their smoky character. Prior to drying with air the green malt is introduced to smoke by lighting a peat fire below the kiln. Back in the day many distilleries would not have had access to other heating materials such as coal or wood and will have used what natural resources were available for drying the malt. In the case of many areas in Scotland, especially Islay, peat was an abundant material. Even after the introduction of better heating sources the practice continued due to the distinctive character it lends to the whisky. By adjusting the level of air flow and temperature, malts of different flavours and colours can be produced. The moisture content of the dried malt is roughly 3 – 6%. The malt is then put through a deculmer machine to remove the tiny rootlets that emerged during germination before being stored ready for the next step in production: Mashing and Fermentation. Take a look at the next step in the production process: Mashing and Fermentation

Whisky Production: Mashing and Fermentation

Whisky is made by distilling beer. As such, we first need to produce a beer before we can distil it. This article covers the brewing process for whisky. Having converted the starch in the barley to fermentable sugars by malting, we now want to extract the sugar. The yeast can then be added in order to produce the alcoholic liquid that will later become whisky. Brewing is separated into two distinct stages: Once the malt has been milled, it is mixed with hot water to extract the sugars and any remaining starch. This stage is known as mashing. The milled malt is initially mixed with water at a temperature of around 64°C. During mashing the grist absorbs water and the sugars begin to dissolve. The remaining starch gelatinises in the hot water, making it easier for the enzymes to hydrolyse it further into fermentable sugars. The first water is then drained off and a second water is added at a temperature of around 70°C. The higher temperature of the second water dissolves further sugars, increasing the extract efficiency. This water is again drained off and a third water is added at temperatures between 80°C and 90°C. The third water ensures that as much sugar as possible is extracted from the mash. The sugar content in the third water is so low however, that it is not used in fermentation but instead recycled and used as the first water for the next mash. Depending on the distillery, occasionally a fourth water is also used. There are three types of vessels in which mashing can take place: mash, lauter and semi-lauter tuns. Traditional mash tuns use large paddles to mix the grain whereas lauter tuns use a series of revolving rakes. Lauter tuns are thereby able to agitate and apply pressure to the mash to a higher degree, increasing extraction efficiency. All other designs between mash and lauter tuns are categorised as semi-lauter tuns. All three have slots in the floor to filter off the sugary liquid, now called wort. Once mashing is completed, the remaining grain (called spent grains or draff) is removed from the mash tun. It is often sold on to farmers to be used as cattle feed due to its nutritional value. The wort now moves to the fermentation tanks, or washbacks, for the next stage: fermentation. The yeast is added to the wort in a large vessel (up to 30,000 litres) known as a washback. These were traditionally made from Oregon pine, although steel is becoming more popular for its ease of cleaning. Many people within the industry swear that the wooden washbacks lend a flavour to the whisky that steel cannot replicate. Distilleries that use steel claim however that tests on both types of washbacks show no significant difference in flavour. After pitching there is an initial lag phase when the yeast acclimatises to its new environment. During this time the yeast begin absorbing nutrients from the wort and producing the enzymes necessary for growth. The yeast then begin to consume sugar and produce alcohol, growing exponentially. As already mentioned the yeast also produce carbon dioxide. This causes the wort to foam and can lead to the washbacks overflowing. Many washbacks have rotating blades above the wort to cut the foam and prevent this from happening. The process also produces heat, raising the temperature of the wort from about 20°C to roughly 32°C. This heat increase must be kept in check as excessive temperatures can exert stress on the yeast and negatively affect the fermentation. Once the nutrients and sugars in the wort have been exhausted, the yeast activity begins to decline. The length of the fermentation process varies between distilleries but is commonly between 48 and 100 hours. The alcoholic liquid, now called wash and very similar to an un-hopped beer, is transferred to the stillhouse for the next stage in whisky production: Distillation. Take a look at the next step in the production process: Distillation

What is Whisky Made From?

Beer. At least that’s the short answer. Much like brandy is made by distilling wine, whisky is made by distilling beer, or at least something very close to beer – I wouldn’t recommend drinking a pint of it. The longer answer, which is still fairly short is that whisky is made from cereals (grains such as barley, corn and rye – not Cornflakes). These grains are combined with water to produce a sugary mixture known as wort, which is then fermented to produce an alcoholic liquid (similar to beer) called wash. The wash is distilled to increase the alcohol content, while reducing unwanted and concentrating desired aromas before being aged, or matured, in wooden casks. A single malt whisky is a malt whisky produced by a single distillery, i.e. not a blend of several distilleries’ malts. A single malt however does not have to come from a single barrel (which would be a single cask malt whisky) but is commonly a mix of several casks from the distillery, allowing the manufacturers to achieve a higher level of consistency in their product despite small variations between batches and casks. Not quite. Each whisky style or whisky producing region has their own set of regulations dictating when the distilled spirit is allowed to be labelled as whisky. For example, the Scotch Whisky Regulations 2009 set forth that “Scotch Whisky” means a whisky:

produced entirely in Scotland;
that has been distilled at an alcoholic strength by volume of less than 94.8 per cent so that the distillate has an aroma and taste derived from the raw materials used in its production;
that has been matured entirely in an excise warehouse or a permitted place in Scotland in oak casks of a capacity not exceeding 700 litres for a period of not less than three years;
to which no substance has been added except water and/or plain caramel colouring; and
that is bottled at a minimum alcoholic strength by volume of 40%.

We will cover the regulations of each style/region (Bourbon Whiskey, Rye Whisky, Japanese Whisky) when we look at each of these whiskies in more detail in future articles. Take a look at the first step in the production process: Malting barley